Crystal Structure of (R)-3-Phenoxy-2-propanol-1-benzylammonium (R)-2-Phenoxypropionate
نویسندگان
چکیده
منابع مشابه
Crystal structure of r-1,c-2-dibenzoyl-t-3,t-4-bis(2-nitrophenyl)cyclobutane
The condensation reaction of aceto-phenone (1-phenyl-ethan-1-one) with 2-nitro-benzaldehyde in the molten state yielded the expected chalcone, (E)-3-(2-nitro-phen-yl)-1-phenyl-prop-2-en-1-one, and, unexpectedly, the title compound, C30H22N2O6, which results from the syn head-to-head [2 + 2] cyclo-addition of the chalcone. The mol-ecular structure of the dimer shows that the four benzene rings o...
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(R)-1-Chloro-3-(1-naphthyloxy)-2-propanol, which is the key intermediate of (S)-propranolol, was successfully prepared via enantioselective transesterification catalyzed by lipase under ultrasound irradiation. Compared with conventional shaking, the enzyme activity and enantioselectivity were dramatically increased under ultrasound exposure. Effects of various reaction conditions on the synthet...
متن کاملCrystal structure of (+)-(R)-3-methyl-1-(1'-phenyl-ethyl)-1H-pyridin-2-one.
wide interest because the 1H-pyridin-2-ones obtained in this process are versatile synthetic building blocks in the synthesis of alkaloids,1–5 although little has been done concerning their use in asymmetric synthesis. This contrasts with the large use of chiral piperidones, which have recently been reported. The synthetic method proceeds first through the addition of the hydroxide anion at pos...
متن کاملCrystal structure of (-)-(1'R)-1-(2'-hydroxy-1'-phenyl-ethyl)-1H-pyridin-2-one.
wide interest because the 1H-pyridin-2-ones obtained in this process are versatile synthetic building blocks in the synthesis of alkaloids.1–5 The title compound, (–)-(1′R)-1-(2′-hydroxy-1′-phenyl-ethyl)1H-pyridin-2-one II, was prepared by stirring a solution of pyridinium salt, I (4.0 mmol), in water (25 ml) and cooled to 5 ̊C (Scheme 1). A solution of K3Fe(CN)6 (11 eq.) in water (30 ml) was ad...
متن کاملCrystal structure and electronic properties of 2-amino-2-methyl-1-propanol (AMP) carbamate.
A crystal structure of a carbamate of 2-amino-2-methyl-1-propanol (AMP-carbamate) has been elucidated and its structural and electronic properties investigated by density functional theory calculations and natural bond orbital analyses.
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ژورنال
عنوان ژورنال: Analytical Sciences: X-ray Structure Analysis Online
سال: 2005
ISSN: 1348-2238
DOI: 10.2116/analscix.21.x25